Metal-hydride air secondary batteries Metal-hydride air secondary batteries

Metal-hydride air secondary batteries

Metal-hydride air secondary batteries

Metal-hydride air secondary batteries have the Ni positive electrode of nickel-metal hydride batteries replaced with air (oxygen) to solve the problem of low energy density in alkaline secondary batteries and to achieve both high energy density and safety.

Features of metal-hydride air secondary batteries

Positive material: Oxygen in air
⇒ Unlimited positive capacity (high capacity)
Negative material: MH alloy
⇒ No dissolution precipitation reaction
(MH: Stable reaction, Li: unstable reaction)
Electrolyte: Alkaline solution
⇒ High power and high safety
Battery reaction
Battery reaction pattern diagram

FDK's original technology

FDK is developing metal-hydride air secondary batteries with an air electrode that uses BiRu oxide (BRO catalyst) as an oxygen reduction catalyst and uses a superlattice hydrogen absorbing alloy for the negative electrode.
The features of metal-hydride air secondary batteries developed by FDK are as follows.
  • The air electrode uses a BRO catalyst that is durable in charging and has a stable charge-discharge cycle performance
  • Achieves stable charge-discharge cycle performance with an active structure that sends air to the battery
  • Cells can be stacked and have low resistance due to adoption of bipolar type cells

Development of air electrode using BRO catalyst (Bi2Ru2O7-x)

With the cooperation of Professor Morimitsu of Doshisha University, we have developed an air electrode that is stable during charging and discharging using an BRO catalyst with a pyrochlore-type crystal structure.
Model of BRO pyrochlore type crystal structure
SEM/TEM images of BRO

Development of active structure cells

We are developing a stackable 10Ah cell by designing a flow path board while calculating the pressure loss etc. to deliver air using our original CAE technology.
Air flow simulation using CAE technology
Stackable 10Ah cell (developed)